Ключевые публикации

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Наиболее значимые публикации сотрудников Лаборатории исследования механизмов каталитических реакций:

Монографии

• Evgenii Talsi, Konstantin Bryliakov. Applications of EPR and NMR Spectroscopy in Homogeneous Catalysis // Boca Raton: CRC Press, 2017, 229 pages. ISBN 978-1-4987-4263-4 (Hardback).


• Bryliakov K. P. Environmentally Sustainable Catalytic Asymmetric Oxidations // Boca Raton: CRC Press, 2015, 162 pages. ISBN 978-1-4665-8857-8 (Hardback).

Статьи

• K. P. Bryliakov, Catalytic Asymmetric Oxygenations with the Environmentally Benign Oxidants H₂O₂ and O₂. Chem. Rev. 2017, 117, 11406–11459.


• N. V. Semikolenova, W. H. Sun, I. E. Soshnikov, M. A. Matsko, O. V. Kolesova, V. A. Zakharov, K. P. Bryliakov, Origin of "Multisite-like" Ethylene Polymerization Behavior of the Single-Site Nonsymmetrical Bis(imino)pyridine Iron(II) Complex in the Presence of Modified Methylaluminoxane. ACS Catalysis, 2017, 7, 2868-2877.


• A. M. Zima, O. Yu. Lyakin, R. V. Ottenbacher, K. P. Bryliakov, E. P. Talsi, Iron-Catalyzed Enantioselective Epoxidations with Various Oxidants: Evidence for Different Active Species and Epoxidation Mechanisms. ACS Catalysis, 2017, 7, 60–69. ACS Editors' Choice article.


• Zima, A. M.; Lyakin, O. Yu.; Ottenbacher, R. V.; Bryliakov, K. P.; Talsi, E. P. Dramatic Effect of Carboxylic Acid on the Electronic Structure of the Active Species in Fe(PDP)-Catalyzed Asymmetric Epoxidation. ACS Catalysis, 2016, 6, 5399–5404.


• Roman V. Ottenbacher, Denis G. Samsonenko, Evgenii P. Talsi, and Konstantin P. Bryliakov, Enantioselective Epoxidations of Olefins with Various Oxidants on Bioinspired Mn Complexes: Evidence for Different Mechanisms and Chiral Additive Amplification, ACS Catalysis, 2016, 6, 979-988.


• Roman V. Ottenbacher, Evgenii P. Talsi, and Konstantin P. Bryliakov. Mechanism of Selective C-H Hydroxylation Mediated by Manganese-Aminopyridine Enzyme Models. ACS Catalysis, 2015, 5, 39-44.


• Oleg Yu. Lyakin, Alexandra M. Zima, Denis G. Samsonenko, Konstantin P. Bryliakov, Evgenii P. Talsi, EPR Spectroscopic Detection of the Elusive Fe^V═O Intermediates in Selective Catalytic Oxofunctionalizations of Hydrocarbons Mediated by Biomimetic Ferric Complexes. ACS Catalysis, 2015, 5, 2702-2707.


• Roman V. Ottenbacher, Denis G. Samsonenko, Evgenii P. Talsi, and Konstantin P. Bryliakov. Highly Enantioselective Bioinspired Epoxidation of Electron-Deficient Olefins with H₂O₂ on Aminopyridine Mn Catalysts. ACS Catalysis, 2014, 4, 1599-1606.


• K. P. Bryliakov, E. P. Talsi, Active sites and mechanisms of bioinspired oxidation with H₂O₂, catalyzed by non-heme Fe and related Mn complexes. Coord. Chem. Rev. 2014, 276, 73-96.


• Igor E. Soshnikov, Nina V. Semikolenova, Vladimir A. Zakharov, Heiko M. Möller, Franz Ölscher, Anna Osichow, Inigo Göttker-Schnettmann, Stefan Mecking, Evgenii P. Talsi and Konstantin P. Bryliakov. Formation and Evolution of Chain-Propagating Species Upon Ethylene Polymerization with Neutral Salicylaldiminato Nickel(II) Catalysts. Chem. Eur. J. 2013, 19, 11409-11417.


• Bryliakov, K. P., Talsi, E. P. Frontiers of mechanistic studies of coordination polymerization and oligomerization of α-olefins. Coord. Chem. Rev. 2012, 256, 2994-3007.


• Lyakin O. Yu, Ottenbacher R. V., Bryliakov, K. P., Talsi, E. P. Asymmetric Epoxidations with H₂O₂ on Fe and Mn Aminopyridine Catalysts: Probing the Nature of Active Species by Combined Electron Paramagnetic Resonance and Enantioselectivity Study. ACS Catalysis, 2012, 2, 1196-1202.


• E. P. Talsi, K. P. Bryliakov. Chemo- and stereoselective C-H oxidations and epoxidations/cis-dihydroxylations with H₂O₂, catalyzed by non-heme iron and manganese complexes. Coord. Chem. Rev., 2012, 256, 1418-1434.


• Lyakin, O. Yu., Bryliakov, K. P., Britovsek, G. J. P., Talsi, E. P. EPR Spectroscopic Trapping of the Active Species of Nonheme Iron-Catalyzed Oxidation. J. Am. Chem. Soc., 2009, 131, 10798-10799.


• Nuzhdin, A. L.; Dybtsev, D. N.; Bryliakov, K. P.; Talsi, E. P.; Fedin, V. P. Enantioselective Chromatographic Resolution and One-Pot Synthesis of Enantiomerically Pure Sulfoxides over a Homochiral Zn-Organic Framework. J. Am. Chem. Soc. 2007, 129, 12958-12959.