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Contributions to Green Chemistry, Clean Technology and Sustainability
By Sir John Meurig Thomas (University of Cambridge, UK)
“This book will certainly become a milestone in the attempts
to develop unifying concepts in catalysis.”
Gerhard Ertl
Nobel Laureate, Chemistry, 2007
For far too long chemists and industrialists have relied on the use of aggressive reagents such as nitric and sulphuric acids, permanganates and dichromates to prepare the massive quantities of both bulk and fine chemicals that are needed for the maintenance of civilised life — mate-rials such as fuels, fabrics, foodstuffs, fertilisers and pharmaceuticals. Such aggressive reagents generate vast quantities of environmentally harmful and often toxic by-products, including the oxides of nitrogen, of metal oxides and carbon dioxide.
Now, owing to recent advances made in the synthesis of nanoporous solids, it is feasible to design new solid catalysts that enable benign, mild oxidants to be used, frequently without utilising solvents, to manufacture the products that the chemical, pharmaceutical, agro- and bio-chemical industries require. These new solid agents are designated single-site heterogeneous catalysts (SSHCs). Their principal characteristics are that all the active sites present in the high-area solids are identical in their atomic environment and hence in their energy of interaction with reactants, just as in enzymes.
Single-site heterogeneous catalysts now occupy a position of growing importance both academically and in their potential for commercial exploitation. This text, the only one devoted to such catalysts, dwells both on principles of design and on applications, such as the benign synthesis of nylon 6 and vitamin B3. It equips the reader with unifying insights required for future catalytic adventures in the quest for sustainability in the materials used by humankind.
Anyone acquainted with the language of molecules, including undergraduates in the physical and biological sciences, as well as graduates in engineering and materials science, should be able to assimilate the principles and examples presented in this book. Inter alia, it describes how clean technology and ‘green’ processes may be carried out in an environmentally responsible manner.
Contents
Basics and Background:
Microporous Open Structures:
Mesoporous Open Structures:
Readership: Students, professionals, some industrial scientists.
Journal titles listed alphabetically | 2011 Impact Factor |
Advanced Powder Technology | 1.612 |
Applied Catalysis A, General | 3.903 |
Applied Catalysis B: Environmental | 5.625 |
Applied Energy | 5.106 |
Biochemical Engineering Journal | 2.645 |
Catalysis Communications | 2.986 |
Catalysis Today | 3.407 |
Chemical Engineering & Processing: Process Intensification | 1.924 |
Chemical Engineering Journal | 3.461 |
Chemical Engineering Research and Design | 1.968 |
Chemical Engineering Science | 2.431 |
Chinese Journal of Chemical Engineering | 0.826 |
Combustion and Flame | 3.585 |
Computers and Chemical Engineering | 2.320 |
Desalination | 2.590 |
Dyes and Pigments | 3.126 |
Filtration & Separation | 0.111 |
Fluid Phase Equilibria | 2.139 |
Food and Bioproducts Processing | 1.940 |
Fuel | 3.248 |
Fuel Processing Technology | 2.945 |
Hydrometallurgy | 2.027 |
International Journal of Adhesion and Adhesives | 2.170 |
International Journal of Mineral Processing | 1.304 |
Journal of Aerosol Science | 2.447 |
Journal of Bionic Engineering | 1.023 |
Journal of Catalysis | 6.002 |
Journal of Colloid And Interface Science | 3.070 |
Journal of Food Engineering | 2.414 |
Journal of Hazardous Materials | 4.173 |
Journal of Industrial and Engineering Chemistry | 1.977 |
Journal of Loss Prevention in the Process Industries | 0.913 |
Journal of Membrane Science | 3.850 |
Journal of Molecular Catalysis. A, Chemical | 2.947 |
Journal of Molecular Catalysis. B, Enzymatic | 2.735 |
Journal of Natural Gas Chemistry | 1.348 |
Journal of Process Control | 1.696 |
Journal of the Taiwan Institute of Chemical Engineers | 2.110 |
Microporous and Mesoporous Materials | 3.285 |
Minerals Engineering | 1.352 |
Particuology | 1.423 |
Powder Technology | 2.080 |
Proceedings of the Combustion Institute | 3.633 |
Process Biochemistry | 2.627 |
Process Safety and Environmental Protection | 1.050 |
Progress in Energy and Combustion Science | 14.220 |
Reactive and Functional Polymers | 2.479 |
Separation and Purification Technology | 2.921 |
The Journal of Supercritical Fluids | 2.860 |
Utilities Policy | 0.804 |
Water Research | 4.86 |
Journal Citation Reports®, published by Thomson Reuters, 2012
www.elsevier.com/chemicalengineering
ChemCatChem
Artificial Metalloenzymes
http://onlinelibrary.wiley.com/doi/10.1002/cctc.201000011/full
Fiora Rosati, Dr. Gerard Roelfes
Catalytic Addition of Aromatic C–H Bonds to Vinylsilanes in the Presence of Ru/CeO2
http://onlinelibrary.wiley.com/doi/10.1002/cctc.201000144/full
Hiroki Miura, Dr. Kenji Wada, Dr. Saburo Hosokawa, Prof. Dr. Masashi Inoue
Enantiopure Monoprotected cis-1,2-Diaminocyclohexane: One-Step Preparation and Application in Asymmetric Organocatalysis
http://onlinelibrary.wiley.com/doi/10.1002/cctc.201000104/full
Prof. Dr. A. Berkessel, M.-C. Ong, M. Nachi, Dr. J.-M. Neudörfl
Aqueous-Phase Hydrogenation of Acetic Acid over Transition Metal Catalysts
http://onlinelibrary.wiley.com/doi/10.1002/cctc.201000134/full
Hakan Olcay, Dr. Lijun Xu, Dr. Ye Xu, Prof. George W. Huber
ChemSusChem
Catalytic Oxy-Functionalization of Methane and Other Hydrocarbons: Fundamental Advancements and New Strategies
http://onlinelibrary.wiley.com/doi/10.1002/cssc.201000319/full
Joanna R. Webb, Tamara Bolaño and T. Brent Gunnoe
Catalytic Oxidative Dehydration of Glycerol over a Catalyst with Iron Oxide Domains Embedded in an Iron Orthovanadate Phase
http://onlinelibrary.wiley.com/doi/10.1002/cssc.201000245/full
Feng Wang, Jie Xu, Jean-Luc Dubois and Wataru Ueda
A Tandem Water-Splitting Device Based on a Bio-inspired Manganese Catalyst
http://onlinelibrary.wiley.com/doi/10.1002/cssc.201000171/full
Robin Brimblecombe, Annette Koo, G. Charles Dismukes, Gerhard F. Swiegers and Leone Spiccia
Advanced Synthesis & Catalysis
Carbenes Made Easy: Formation of Unsymmetrically Substituted
N-Heterocyclic Carbene Complexes of Palladium(II), Platinum(II) and Gold(I) from Coordinated Isonitriles and their Catalytic Activity
http://onlinelibrary.wiley.com/doi/10.1002/adsc.201000472/full
A. Stephen K. Hashmi, Christian Lothschütz, Constantin Böhling, Tobias Hengst, Christoph Hubbert, Frank Rominger
Finding Furfural Hydrogenation Catalysts via Predictive Modelling
http://onlinelibrary.wiley.com/doi/10.1002/adsc.201000308/full
Zea Strassberger, Maurice Mooijman, Eelco Ruijter, Albert H. Alberts, Ana G. Maldonado, Romano V. A. Orru, Gadi Rothenberg
Angewandte Chemie IE
An Efficient Titanium Catalyst for Enantioselective Cyanation of Aldehydes: Cooperative Catalysis
http://onlinelibrary.wiley.com/doi/10.1002/anie.201002127/full
Zhipeng Zhang, Zheng Wang, Ruzhou Zhang and Kuiling Ding
Preparation and Regioselective Diels–Alder Reactions of Borylbenzynes: Synthesis of Functionalized Arylboronates
http://onlinelibrary.wiley.com/doi/10.1002/anie.201002191/full
Takashi Ikawa, Akira Takagi, Yurio Kurita, Kozumo Saito, Kenji Azechi, Masahiro Egi, Keisuke Kakiguchi, Yasuyuki Kita and Shuji Akai
Palladium-Catalyzed β Arylation of Carboxylic Esters
http://onlinelibrary.wiley.com/doi/10.1002/anie.201003544/full
Alice Renaudat, Ludivine Jean-Gérard, Rodolphe Jazzar, Christos E. Kefalidis, Eric Clot and Olivier Baudoin
Chemistry – A European Journal
Unifying Metal and Bronsted Acid Catalysis—Concepts, Mechanisms, and Classifications
http://onlinelibrary.wiley.com/doi/10.1002/chem.201001140/full
Magnus Rueping, Rene M. Koenigs, Iuliana Atodiresei
Selective Iron-Catalyzed Oxidation of Phenols and Arenes with Hydrogen Peroxide: Synthesis of Vitamin E Intermediates and Vitamin K3
http://onlinelibrary.wiley.com/doi/10.1002/chem.201001429/full
Konstanze Möller, Gerrit Wienhöfer, Kristin Schröder, Benoit Join, Kathrin Junge, Matthias Beller
Modulation of the Aerobic Oxidative Polymerization in Phenylazomethine Dendrimers Assembling Copper Complexes
http://onlinelibrary.wiley.com/doi/10.1002/chem.201001516/full
Takane Imaoka, Yuki Kawana, Masahiro Tsuji, Kimihisa Yamamoto
Chemistry – An Asian Journal
Catalytic Enantioselective Arylation of Glyoxylate with Arylsilanes: Practical Synthesis of Optically Active Mandelic Acid Derivatives
http://onlinelibrary.wiley.com/doi/10.1002/asia.201000522/full
Kohsuke Aikawa, Yūta Hioki, Koichi Mikami
A Heterobimetallic Ni/La-salan Complex for Catalytic Asymmetric Decarboxylative 1,4-Addition of Malonic Acid Half-Thioester
http://onlinelibrary.wiley.com/doi/10.1002/asia.201000540/full
Makoto Furutachi, Shinsuke Mouri, Shigeki Matsunaga, Masakatsu Shibasaki
Helvetica Chimica Acta
Enzyme-Catalyzed Stereoselective Synthesis of Two Novel Carbasugar Derivatives
http://onlinelibrary.wiley.com/doi/10.1002/hlca.201000213/pdf
Ayşegül Gümüş, Cihangir Tanyeli
Chinese Journal of Chemistry
Theoretical Investigation on the Mechanism and Design of Catalysts for Nitrolysis of Hexamine
http://onlinelibrary.wiley.com/doi/10.1002/cjoc.201090264/pdf
Liangwei Shi, Gang Zhao, Yazhu Zhang, Changwu Zheng, Guangming Qin, Jian Lü
Zeitschrift für anorganische und allgemeine Chemie
Progress in the Compilation of an Oxovanada-Silsesquioxane Portfolio and Catalytic Activity of Organometallic Representatives in Ethylene Polymerisation
http://onlinelibrary.wiley.com/doi/10.1002/zaac.201000287/full
Christian Ohde, Christian Limberg, Dennis Schmidt, Markus Enders,Serhiy Demeshko, Christina Knispel
Israel Journal of Chemistry
Highly (≥98%) Selective Trisubstituted Alkene Synthesis of Wide Applicability via Fluoride-Promoted Pd-Catalyzed Cross-Coupling of Alkenylboranes
http://onlinelibrary.wiley.com/doi/10.1002/ijch.201000051/full
Ei-ichi Negishi, Tomas Tobrman, Honghua Rao, Shiqing Xu, Ching-Tien Lee
Cobalt-Catalyzed Cross-Coupling Reactions of Aryl Halides
http://onlinelibrary.wiley.com/doi/10.1002/ijch.201000032/full
Corinne Gosmini, Aurélien Moncomble
Macromolecular Rapid Communications
Discrete Metal Catalysts for Stereoselective Ring-Opening Polymerization of Chiral Racemic β-Lactones
http://onlinelibrary.wiley.com/doi/10.1002/marc.201000114/full
Jean-François Carpentier
Macromolecular Reaction Engineering
Reducing ATRP Catalyst Concentration in Batch, Semibatch and Continuous Reactors
http://onlinelibrary.wiley.com/doi/10.1002/mren.200900086/full
Nicky Chan, Michael F. Cunningham, Robin A. Hutchinson
Macromolecular Chemistry & Physics
Synthesis of Narrowly Distributed ω-Telechelic Hyperbranched Polyethylenes by Efficient End-Capping of Pd-Diimine-Catalyzed Ethylene "Living" Polymerization with Styrene Derivatives
http://onlinelibrary.wiley.com/doi/10.1002/macp.201000196/full
Shiyun Li, Zhibin Ye
Ni-Catalyzed Polymerization of Poly(3-alkoxythiophene)s
http://onlinelibrary.wiley.com/doi/10.1002/macp.201000561/full
Karlien Van den Bergh, Julien De Winter, Pascal Gerbaux, Thierry Verbiest, Guy Koeckelberghs
Macromolecular Theory and Simulations
Determination of the Catalytic Sites for Ziegler-Natta Homo-Polymerization from GPC Data
http://onlinelibrary.wiley.com/doi/10.1002/mats.201000040/full
Sridhar V. Maddipati, W. Nicholas Delgass, James M. Caruthers
Chemical Engineering & Technology
Glycerol-Reforming Kinetics Using a Pt/C Catalyst
http://onlinelibrary.wiley.com/doi/10.1002/ceat.201000055/pdf
Parag N. Sutar, Prakash D. Vaidya, Alirio E. Rodrigues
Post-Plasma Catalysis for Methane Partial Oxidation to Methanol: Role of the Copper-Promoted Iron Oxide Catalyst
http://onlinelibrary.wiley.com/doi/10.1002/ceat.201000092/pdf
Lin Chen, Xingwang Zhang, Liang Huang, Lecheng Lei
Chemie Ingenieur Technik
Dehydratisierung von Glycerin zu Acrolein in der Gasphase an geträgerten Heteropolysäure-Katalysatoren
http://onlinelibrary.wiley.com/doi/10.1002/cite.201000026/pdf
Udo Armbruster, Hanan Atia, Andreas Martin
Veredelung nachwachsender Rohstoffe durch Selektivoxidation mit Goldkatalysatoren
http://onlinelibrary.wiley.com/doi/10.1002/cite.201000070/pdf
Ulf Prüße, Katharina Heidkamp, Nadine Decker, Mirko Herrmann, Klaus-Dieter Vorlop
European Journal of Organic Chemistry
Efficient Copper-Catalyzed Direct Amination of Aryl Halides Using Aqueous Ammonia in Water
http://onlinelibrary.wiley.com/doi/10.1002/ejoc.201001150/full
Fei Meng, Xinhai Zhu, Ying Li, Jianwei Xie, Bo Wang, Junhua Yao, Yiqian Wan
Transition-Metal-Catalyzed Direct C–H Alkenylation, Alkynylation, Benzylation, and Alkylation of (Hetero)arenes
http://onlinelibrary.wiley.com/doi/10.1002/ejoc.201000928/full
Samir Messaoudi, Jean-Daniel Brion and Mouâd Alami
European Journal of Inorganic Chemistry
Donor-Functionalised Expanded Ring N-Heterocyclic Carbenes: Highly Effective Ligands in Ir-Catalysed Transfer Hydrogenation
http://onlinelibrary.wiley.com/doi/10.1002/ejic.201000680/full
Abeer Binobaid, Manuel Iglesias, Dirk Beetstra, Athanasia Dervisi, Ian Fallis and Kingsley J. Cavel